SYNTHESIS AND STRUCTURE OF THE COMPLEX OF COBALT(II) ACETATE AND SUCCINIC ACID WITH THE SODIUM SALT

  • Erkabay ESHCHANOV Urganch davlat universiteti dotsenti
  • Shodlik HASANOV Xorazm Ma’mun akademiyasi ilmiy ishlar bo‘yicha rais o‘rinbosari
  • Oybek XUDOYBERGANOV Xorazm Ma’mun akademiyasi katta ilmiy xodimi
  • Zubayda ABDULLAYEVA Xorazm Ma’mun akademiyasi katta ilmiy xodimi
  • Shohida XO‘SINOVA Urganch davlat universiteti magistranti
  • Sanobar KALANDAROVA Urganch davlat universiteti magistranti
Keywords: Cobalt(II) acetate, succinic acid with the sodium salt, ligand, thermal analysis, SEM-EDX, X-ray phase and X-ray structural analysis, complex compound, coordination number, Mercury program, coordination capacity, complex compound stability

Abstract

This article highlights the research results on the synthesize of a new heterometallic complex compound of cobalt(II) acetate and succinic acid with the sodium salt and the determination of their composition, structure and properties by physico-chemical methods: scanning electron microscope-energy dispersive analysis (SEM-EDX), X-ray phase analysis, thermal analysis and X-ray structural analysis. The central atom of the complex compound is cobalt, the oxygen atom of the carboxyl group of the acetate residue and the sodium salt of succinic acid are interconnected through the oxygen atom of the carboxyl group, forming a complex compound with a coordination number of 6.

References

‘zbekiston Respublikasi Prezidentining 2022 yil 28 yanvardagi PF-60-sonli “2022-2026 yillarga mo‘ljallangan Yangi O‘zbekistonning taraqqiyot strategiyasi to‘g‘risida”gi Farmoni.
2. Шакирова Ю.Р. Гомо- и гетерометаллические люминесцентные комплексы металлов подгруппы меди: син-тез и исследование фотофизических свойств: дис. ... канд. хим. наук : 02.00.01. − СПб., 2014. − 181 л.
3. Synthesis and properties of the coordination compound of calcium stearate with thiocarbamide // Khasanov Sh.B., Ibodullaeva T.A., Abdullaeva Z.Sh., Khudoyberganov, O.I. Azerbaijan Chemical Journal , 2023, 2023(2), P-111–115.
4. Прямой синтез координационных соединений. Под ред. акад. НАН Украины Скопенко В. В. - Киев: Вент, 1997.-175 с.
5. Корусенко П. М., Несов С. Н., Ивлев К. Е. Морфология, структура и электрохимические свойства композита MnOx @ CNTs: исследование методами SEM, EDX, XPS и CVA // Омский научный вестник. 2022. № 2 (182). С. 86–92. DOI: 10.25206/1813-8225-2022-182-86-92.
6. Ковба П. М., Трунов В. К. Рентгенофазовый анализ. - М.: МГУ, 1976. - 232 с.
7. Топор Н.Д., Огородова Л.П., Мельчакова Л.В. Термический анализ минералов и неорганических соединений. Москва: Изд-во МГУ, 1987. - С.190.
8. Шаталова Т.Б., Шляхтин О.А., Веряева Е. Методы термического анализа. – Москва: 2011. – 72 с.
9. Савицкая Л.К. Рентгеноструктурный анализ: учебное пособие// Томск: СКК-Пресс, 2006, стр.274.
10. Macrae C.F, Bruno I.J, Chisholm J.A. et. al. Mercury CSD 2.0 – new features for the visualization and investigation of crystal structures // J. Appl. Cryst. -2008. –V.41. -P.466-470.
11. Sheldrick G.M. // SHELXS97, SHELXL97, Programs for Crystal Structures Solution and Refinement, University of Göttingen, Göttingen, Germany. - 1997.
12. G.M. Sheldrick, Acta Crystallogr., 2015, A71, 3.
Published
2024-03-30
How to Cite
Erkabay ESHCHANOV, Shodlik HASANOV, Oybek XUDOYBERGANOV, Zubayda ABDULLAYEVA, Shohida XO‘SINOVA, & Sanobar KALANDAROVA. (2024). SYNTHESIS AND STRUCTURE OF THE COMPLEX OF COBALT(II) ACETATE AND SUCCINIC ACID WITH THE SODIUM SALT. News of the NUUz, 3(3.1), 470-475. https://doi.org/10.69617/uzmu.v3i3.1.1897