СИНТЕЗ И ИССЛЕДОВАНИЕ КОМПЛЕКСНЫХ СОЕДИНЕНИЙ УРАНИЛ ИОНА C 2-АМИНО-1-МЕТИЛБЕНЗИМИДАЗОЛОМ
Ключевые слова:
: комплексное соединение, диэтилдитиокарбамат натрия, 2-амино-1-метилбензимидазол, состав, структура, свойства
Аннотация
Синтезированы и исследованы комплексные соединения уранил-иона c 2-амино-1-метилбензимидазолом (МАВ) и диэтилдитиокарбаматом (DEDTK). Состав и строение полученных комплексных соединений установлены методами сканирующей электронной микроскопии с энергодисперсионным анализом, ИК-, Раман-спектроскопии, дифференциально-термическим анализом. Установлена зависимость состава, структуры и свойств комплексных соединений от природы комплексообразователя и способов координации лиганда.
Литература
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5. El-Sonbati A.Z., Diab M.A., Morgan S., Seyam H.A. Supramolecular structures for determination and identification of the bond lengths in novel uranyl complexes from their infrared spectra // Journal of Molecular Structure. -2017. -V1154. -P.354-365.
6. ChakrabortyI S., DindaII S., BhattacharyyaII R. and Mukherjee A.K. Syntheses, spectroscopic and X-ray structure analyses of two dioxouranium (VI) complexes: supramolecular framework built from O–H. . .O, C–H. . .O and stacking interactions. // Z. Kristallogr. -2006. -V.221. -P. 606–611.
7. Enriquez A.E., Scott B.L., Neu M.P. Uranium (III)/(IV) nitrile adducts including UI4(NCPh)4, a synthetically useful Uranium (IV) complex // Inorg. Chem. -2005. -V.44. -P. 7403–7413.
8. Oldham W.J., Scott B.L., Abney K.D., Smith W.H., Costa D.A. Chloroheptakis (dimethyl sulfoxide) uranium (IV) trichloride // Acta Cryst. C58. -2002. m139–m140.
9. Daminova Sh.Sh., Kadirova Z.Ch., Sharipov X.T. IR spectroscopic study of transition metals with impregnated sorbents based on Porolas // Uzbekistan chem. journal. -2016. -N6. -P.3-9
10. Gordon H.J., Iain M., Mark J.S., Helen M.S., Collison D., Helliwell M. and McKinney J.D. The structural and spectroscopic characterisation of three actinyl complexes with coordinated and uncoordinated perrhenate: [UO2(ReO4)2(TPPO)3], [{(UO2)(TPPO)3}2(_2-O2)][ReO4]2 and [NpO2(TPPO)4][ReO4] // Dalton Trans 2004, 734-740.
11. Kannan S., Chetty K.V., Venugopal V., Drew G.B. Extraction and coordination studies of the unexplored bifunctional ligand carbamoyl methyl sulfoxide (CMSO) with uranium (VI) and cerium (III) nitrates. Synthesis and structures of [UO2(NO3)2(PhSOCH2CONiBu2)] and [Ce(NO3)3(PhSOCH2CONBu2)2] // J. Chem. Soc. Dalton Trans. -2004. -V.21. -P. 3604–3610.
12. Gatto C.C., Lang E.S., Jagst A., Abram U. Dioxouranium(VI) complexes with 2,6-acetylpyridinebenzoylhydrazones and -semicarbazones // Inorganica chimica acta. -2004. -V.357. -P. 4349–4644.
2. Khedr A.M. and Saad F.A. Synthesis, structural characterization, and antimicrobial efficiency of sulfadiazine azo-azomethine dyes and their bi-homonuclear uranyl complexes for chemotherapeutic use // Turkish Journal of Chemistry. -2015. -V.39. -N2. -P. 267–280.
3. Doris M., Lin H., Andrew E.J., John Y.G., Turner P., Zsolt V., Lorenzo F., Thomas F., Klaus M. Raman spectroscopy of uranium compounds and the use of multivariate analysis for visualization and classification // Forensic Science International. -2015. -V.251 -P.61–68.
4. Sessler J.L., Melfi P.J., and Pantos G.D., Uranium complexes of multidentate N-donor ligands // Coordination chemistry reviews. -2006. -V.250. -N7-8. -P. 816–843.
5. El-Sonbati A.Z., Diab M.A., Morgan S., Seyam H.A. Supramolecular structures for determination and identification of the bond lengths in novel uranyl complexes from their infrared spectra // Journal of Molecular Structure. -2017. -V1154. -P.354-365.
6. ChakrabortyI S., DindaII S., BhattacharyyaII R. and Mukherjee A.K. Syntheses, spectroscopic and X-ray structure analyses of two dioxouranium (VI) complexes: supramolecular framework built from O–H. . .O, C–H. . .O and stacking interactions. // Z. Kristallogr. -2006. -V.221. -P. 606–611.
7. Enriquez A.E., Scott B.L., Neu M.P. Uranium (III)/(IV) nitrile adducts including UI4(NCPh)4, a synthetically useful Uranium (IV) complex // Inorg. Chem. -2005. -V.44. -P. 7403–7413.
8. Oldham W.J., Scott B.L., Abney K.D., Smith W.H., Costa D.A. Chloroheptakis (dimethyl sulfoxide) uranium (IV) trichloride // Acta Cryst. C58. -2002. m139–m140.
9. Daminova Sh.Sh., Kadirova Z.Ch., Sharipov X.T. IR spectroscopic study of transition metals with impregnated sorbents based on Porolas // Uzbekistan chem. journal. -2016. -N6. -P.3-9
10. Gordon H.J., Iain M., Mark J.S., Helen M.S., Collison D., Helliwell M. and McKinney J.D. The structural and spectroscopic characterisation of three actinyl complexes with coordinated and uncoordinated perrhenate: [UO2(ReO4)2(TPPO)3], [{(UO2)(TPPO)3}2(_2-O2)][ReO4]2 and [NpO2(TPPO)4][ReO4] // Dalton Trans 2004, 734-740.
11. Kannan S., Chetty K.V., Venugopal V., Drew G.B. Extraction and coordination studies of the unexplored bifunctional ligand carbamoyl methyl sulfoxide (CMSO) with uranium (VI) and cerium (III) nitrates. Synthesis and structures of [UO2(NO3)2(PhSOCH2CONiBu2)] and [Ce(NO3)3(PhSOCH2CONBu2)2] // J. Chem. Soc. Dalton Trans. -2004. -V.21. -P. 3604–3610.
12. Gatto C.C., Lang E.S., Jagst A., Abram U. Dioxouranium(VI) complexes with 2,6-acetylpyridinebenzoylhydrazones and -semicarbazones // Inorganica chimica acta. -2004. -V.357. -P. 4349–4644.
Опубликован
2024-03-30
Как цитировать
Холида ЖАББОРОВА, Сардор МУРОДОВ, & Шахло ДАМИНОВА. (2024). СИНТЕЗ И ИССЛЕДОВАНИЕ КОМПЛЕКСНЫХ СОЕДИНЕНИЙ УРАНИЛ ИОНА C 2-АМИНО-1-МЕТИЛБЕНЗИМИДАЗОЛОМ. Вестник УзМУ, 3(3.1), 372-376. https://doi.org/10.69617/uzmu.v3i3.1.1850
Раздел
Статьи
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